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Issue Info: 
  • Year: 

    2019
  • Volume: 

    52
  • Issue: 

    2
  • Pages: 

    175-187
Measures: 
  • Citations: 

    0
  • Views: 

    218
  • Downloads: 

    78
Abstract: 

A mixture of 10 wt% CuO-10 wt% FE2O3 supported on cordierite were prepared by wet impregnation. The as-prepared solids doped with Li2O (0. 75-3 mol %) were calcined at 500-900 º C. The crystalline phase, morphology, and surface area were investigated by XRD, HR-TEM and N2-adsoprtion-desorption. Moreover, their photocatalytic activities of samples calcined at 700° C on the degradation of phenol were evaluated under UV-irradiation. The catalytic activity of different solids toward H2O2 decomposition was studied. Nano-materials were used to adsorb dyes as Remazole-Red and Congo-Red from aqueous solution. The sorption process was in good agreement of pseudo-second order equation and the Langmuir equation through their adsorption kinetics and isotherms, respectively. The CuO-FE2O3/ cordierite doped with 0. 75% Li2O at 700 º C adsorbent was found to possess the highest removal efficiency of Remazole-Red and/or Congo-Red dyes and potentially lowering capital and operational costs for \practical applications. The highest removal efficiency of the anionic dyes over 0. 75% Li2O at 700 º C can be discussed by observing the appearance of new active phases as CuO, CuFe2O4 and LiCuO, decreasing the crystallite size of these active phases. 0. 75 mol% Li2O has the greatest activity in H2O2 decomposition reached 700 %. This result may be related to the lowest particle size and the highest surface area of this sample, which also produced a large number of electrons donating active sites for H2O2 decomposition.

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Issue Info: 
  • Year: 

    2018
  • Volume: 

    9
  • Issue: 

    3
  • Pages: 

    209-214
Measures: 
  • Citations: 

    0
  • Views: 

    290
  • Downloads: 

    211
Abstract: 

This review discusses recent developments in the field of nanosized biomaterials and their use in tissue regeneration approaches. The aim is to provide an overview of the research focused on nanoparticle-based strategies to stimulate regeneration. In particular, nanoparticles improve the regenerative capabilities of biomaterials offering ways to control surface and mechanical properties. Moreover, incorporation of nanoparticles within biomaterials increases cellular adhesion, differentiation and integration of stem cells into the surrounding environment. Finally, the drug delivery capabilities of nanoparticles offer additional possibilities to increase the biological performance of biomaterials. As the development of nanoparticles continues, incorporation of this technology in the field of regenerative medicine will ultimately lead to new tools that can diagnose, track and stimulate the growth of new tissues and organs.

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Issue Info: 
  • Year: 

    2012
  • Volume: 

    6
  • Issue: 

    3
  • Pages: 

    7-21
Measures: 
  • Citations: 

    0
  • Views: 

    240
  • Downloads: 

    0
Abstract: 

The photodegradation of Ponceau-S dye was investigated using UV radiation in presence of nanosized FE2O3.Removal efficiency of Ponceau-S was sensitive to the operational parameters such as dye concentration, catalyst dose, pH, contact time, TOC and COD. The photocatalytic treatment of red colored Ponceau-S dye by magnetic nano semiconductor (FE2O3) is an effective, economic and faster mode. The kinetics and isotherm studies were carried out. A simple kinetics model was proposed which confirmed pseudo second order reaction. Langmuir isotherm fitted this study. The optimum conditions for the degradation of the dye were initial concentration 50 mgL-1, pH 8, contact time 20 minutes and catalyst dose 5 gL-1 of FE2O3.The semiconductor photocatalyst was also carried out for SEM and XRD analysis which confirms the utilized semiconductor was nanosized.

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Author(s): 

KOBAYASHI H. | BRECHBIEL M.W.

Issue Info: 
  • Year: 

    2004
  • Volume: 

    5
  • Issue: 

    6
  • Pages: 

    539-549
Measures: 
  • Citations: 

    1
  • Views: 

    189
  • Downloads: 

    0
Keywords: 
Abstract: 

Yearly Impact: مرکز اطلاعات علمی Scientific Information Database (SID) - Trusted Source for Research and Academic Resources

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Issue Info: 
  • Year: 

    2009
  • Volume: 

    43
  • Issue: 

    -
  • Pages: 

    163-170
Measures: 
  • Citations: 

    1
  • Views: 

    127
  • Downloads: 

    0
Keywords: 
Abstract: 

Yearly Impact: مرکز اطلاعات علمی Scientific Information Database (SID) - Trusted Source for Research and Academic Resources

View 127

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Issue Info: 
  • Year: 

    1384
  • Volume: 

    24
Measures: 
  • Views: 

    290
  • Downloads: 

    0
Abstract: 

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Yearly Impact:   مرکز اطلاعات علمی Scientific Information Database (SID) - Trusted Source for Research and Academic Resources

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Issue Info: 
  • Year: 

    2014
  • Volume: 

    11
Measures: 
  • Views: 

    142
  • Downloads: 

    83
Abstract: 

THE PHOTO ELECTROLYSIS OF WATER USING N-TYPE SEMICONDUCTING METAL OXIDE ANODES AND PT CATHODES IS WELL DOCUMENTED. TIO2 (EG=3.0 EV), SRTIO3 (EG=3.3 EV) AND FE2O3 (EG=2.2 EV) ARE PARTICULARLY WELL-STUDIED EXAMPLES. HOWEVER, WHILE ALL OF THESE MATERIALS SHOW CONSIDERABLE PROMISE, THEY FALL SHORT OF BEING THE OPTIMUM ELECTRODE MATERIAL. THREE PRIMARY REQUIREMENTS ARE NEEDED FOR SUCH AN ELECTRODE. IT MUST BE INERT UNDER ANY CONCEIVABLE CHEMICAL OR PHOTO ELECTROCHEMICAL CONDITIONS ENCOUNTERED IN THE CELL. ITS BAND GAP SHOULD BE ON THE ORDER OF 1.5-2.0 EV SO AS TO UTILIZE A LARGE PORTION OF THE SOLAR SPECTRUM. IDEALLY, THE SYSTEM SHOULD OPERATE EFFECTIVELY AT ZERO BIAS SO AS TO OBVIATE THE NEED FOR AN EXTERNAL POWER SUPPLY [1-3]. AGAINST OF GOOD CHEMICAL STABILITY OF TIO2, IT HAS A LARGE BAND GAP. ALTHOUGH FE2O3 HAS THE RIGHT BAND GAP, BUT IT HAS SOME STABILITY PROBLEMS AND SUFFERS FROM POOR ZERO-BIAS CHARACTERISTICS. A WAY TO OVERCOME THESE PROBLEMS CAN BE MAKING THEIR NANO COMPOSITES. IN THIS STUDY, WE HAVE PREPARED FE2O3-TIO2 NANO COMPOSITES BY IMPREGNATION METHOD. BRIEFLY, THE APPROPRIATE AMOUNTS OF NANOPARTICLES OF TIO2 WERE IMMERSED IN FE(NO3)3 SOLUTIONS ITH TO DIFFERENT CONCENTRATIONS FOR 24 HOURS. THEN THE SOLID MATERIALS WERE FILTERED, WASHED FOR SEVERAL TIMES BY DE-IONIZED WATER AND DRIED AT 100OC.THEN DERIED MATERIALS WERE CALCINED UP TO 450OC IN OXYGEN ATMOSPHERE. THE CRYSTAL STRUCTURE AND MORPHOLOGY OF THE PREPARED MATERIALS WERE CERTIFIED BY XRD AND TEM. THE COMPOSITIONS OF NANOCOMPOSITES WERE DETERMINED BY ATOMIC ADSORPTION SPECTROSCOPY ANALYSIS. THE BAND GAPS OF PREPARED MATERIALS WERE DETERMINED BY DIFFUSE REFLECTANCE UV-VIS SPECTROSCOPY. FINALLY, THE ELECTROCHEMICAL STUDIES OF NANOCOMPOSITES AND ALSO FE2O3, CONTAINING CYCLIC VOLTAMMETRY AND ELECTROCHEMICAL IMPEDANCE SPECTROSCOPY, WERECARRIED OUT BY MAKING A CARBON PASTE ELECTRODE CONTAINING THE APPROPRIATE AMOUNTS OF GRAPHITE, N-ECOSAN AND NANOCOMPOSITES OR FE2O3 IN A STANDARD THREE ELECTRODES CELLS CONTAINING OF A PLATINUM GRID, AG/AGCL AND CARBON PASTE AS AUXILIARY, REFERENCE AND WORKING ELECTRODES, RESPECTIVELY, USING A SOLARTRON ELECTROCHEMICAL WORK STATION. THE DIFFERENCE BETWEEN THE ELECTROCHEMICAL BEHAVIORS OF NANO COMPOSITES AND FE2O3 WERE INTERPRETED IN TERMS OF THEIR ELECTRONIC STRUCTURE.

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Issue Info: 
  • Year: 

    2011
  • Volume: 

    2
  • Issue: 

    5
  • Pages: 

    17-22
Measures: 
  • Citations: 

    0
  • Views: 

    2999
  • Downloads: 

    0
Abstract: 

One of the main problems of surface and underground water hazardous concentrations of heavy metals into the precious resources that are. The method this type of filtration to remove contaminants such that is used to capture the mentioned surface. In adsorption sorbent surface area and volume due to the high porosity is able to absorb pollutants and water to separate into their cavities. Because the surface area and volume of porous iron particles having a substantial ability to absorb pollutants from the water able to be. The ability of nano particles a-FE2O3Fe3O4, and  g-FE2O3 ion in the adsorption of heavy metals such as Cr6+, Cu2+, Cd2+ and Ni2+studied and compared.

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Issue Info: 
  • Year: 

    2016
  • Volume: 

    6
  • Issue: 

    11 (21)
  • Pages: 

    43-54
Measures: 
  • Citations: 

    0
  • Views: 

    1072
  • Downloads: 

    0
Abstract: 

In this study, the effect of FE2O3 particle concentration on the protective properties of the Ni-FE2O3 composite coating formed on AISI304 substrate was evaluated. The electrodeposition process was conducted in a plating bath without and with different concentration of FE2O3 particles. The surface morphology and structure was characterized using scanning electron microscope (SEM), Electronic diffraction line scans (EDS) and X-ray diffraction (XRD). The corrosion behavior of the coating was evaluated by measuring the variation of corrosion potential during the immersion time and electrochemical impedance spectroscopy (EIS) method. The results revealed that in pH=4 and a current density of 20 mA/cm2, The precipitation of FE2O3 particles in nickel matrix reached to its maximum value when the concentration of the particles in the electrolyte was 20 g/lit. However, the microhardness results and corrosion behavior of coated samples was revealed that the homogeneous dispersion of second phase particles in matrix plays a dominant role in the promotion of surface and protective properties of the coating. Nickel coating increased the corrosion resistance of AISI304 more than double. The addition of FE2O3 particles into the electroplating bath caused an increase in corrosion resistance of Nickel coating and the coating fabricated in the bath containing 15g/lit FE2O3 provided the highest corrosion resistant which was almost 5 times higher than corrosion resistance of the steel substrate.

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Author(s): 

KOUTI M. | MATOURI L.

Journal: 

Scientia Iranica

Issue Info: 
  • Year: 

    2010
  • Volume: 

    17
  • Issue: 

    1 (TRANSACTION F: NANOTECHNOLOGY)
  • Pages: 

    73-78
Measures: 
  • Citations: 

    0
  • Views: 

    1769
  • Downloads: 

    1217
Abstract: 

In this paper we describe a facile method for the synthesis of Cu2O nanoparticles by reduction of Fehling's solution, using glucose as reducing agent. Copper sulfate is used as a precursor with potassium sodium tartarate in an alkaline media to produce Fehling's solution. The precipitation of Cu2O nanoparticles from this solution in the presence of glucose was controlled by addition of SLES or Triton-X 100 as surfactants. The reactions have been carried out at 60°C with high repeatability. The purification process of the Cu2O product does not require expensive methods, since a solid product is obtained from a reaction in liquid phase. The resulting Cu2O nanoparticles were characterized by X-Ray Diffraction (XRD), Scanning Electron Microscopy (SEM), Energy-Dispersive X-ray spectroscopy (EDX), Transmission Electron Microscopy (TEM) and Fourier-transform infrared (FTIR) spectroscopy.

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